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For First Time, Researchers Measure Forces That Align Crystals and Help Them Snap Together

For the first time, researchers have measured the force that draws tiny crystals together and visualized how they swivel and align. Called van der Waals forces, the attraction provides insights into how crystals self-assemble, an activity that occurs in a wide range of cases in nature, from rocks to shells to bones.

Video Captures Bubble-Blowing Battery in Action

PNNL researchers have created a unique video that shows oxygen bubbles inflating and later deflating inside a tiny lithium-air battery. The knowledge gained from the video could help make lithium-air batteries that are more compact, stable and can hold onto a charge longer.

Study Offers New Theoretical Approach to Describing Non-Equilibrium Phase Transitions

Two physicists at Argonne offered a way to mathematically describe a particular physics phenomenon called a phase transition in a system out of equilibrium. Such phenomena are central in physics, and understanding how they occur has been a long-held and vexing goal; their behavior and related effects are key to unlocking possibilities for new electronics and other next-generation technologies.

Berkeley Lab Scientists Discover New Atomically Layered, Thin Magnet

Berkeley Lab scientists have found an unexpected magnetic property in a 2-D material. The new atomically thin, flat magnet could have major implications for a wide range of applications, such as nanoscale memory, spintronic devices, and magnetic sensors.

Stabilizing Molecule Could Pave Way for Lithium-Air Fuel Cell

Lithium-oxygen fuel cells boast energy density levels comparable to fossil fuels and are thus seen as a promising candidate for future transportation-related energy needs.

Scientists Identify Chemical Causes of Battery "Capacity Fade"

Researchers at Argonne National Laboratory identified one of the major culprits in capacity fade of high-energy lithium-ion batteries.

Modeling Reveals How Policy Affects the Adoption of Solar Energy Photovoltaics in California

Researchers at the University of California, Riverside, inspired by efforts to promote green energy, are exploring the factors driving commercial customers in Southern California, both large and small, to purchase and install solar photovoltaic (PV) systems. As the group reports this week in the Journal of Renewable and Sustainable Energy, they built a model for commercial solar PV adoption to quantify the impact of government incentives and solar PV costs.

Machine Learning Dramatically Streamlines Search for More Efficient Chemical Reactions

A catalytic reaction may follow thousands of possible paths, and it can take years to identify which one it actually takes so scientists can tweak it and make it more efficient. Now researchers at the Department of Energy's SLAC National Accelerator Laboratory and Stanford University have taken a big step toward cutting through this thicket of possibilities.

Freezing Lithium Batteries May Make Them Safer and Bendable

Columbia Engineering Professor Yuan Yang has developed a new method that could lead to lithium batteries that are safer, have longer battery life, and are bendable, providing new possibilities such as flexible smartphones. His new technique uses ice-templating to control the structure of the solid electrolyte for lithium batteries that are used in portable electronics, electric vehicles, and grid-level energy storage. The study is published online April 24 in Nano Letters.

New Study Reveals the Mystery Behind the Formation of Hollowed Nanoparticles During Metal Oxidation

In a newly published <i>Science</i> paper, Argonne and Temple University researchers reveal new knowledge about the behavior of metal nanoparticles when they undergo oxidation, by integrating X-ray imaging and computer modeling and simulation. This knowledge adds to our understanding of fundamental processes like oxidation and corrosion.


OU Engineering Professor Receives National Science Foundation Early CAREER Award

A University of Oklahoma Gallogly College of Engineering professor, Steven P. Crossley, is the recipient of a five-year, National Science Foundation Early CAREER Award in the amount of $548,829 for research that can be used to understand catalysts that are important for a broad range of chemical reactions ranging from the production of renewable fuels and chemicals for natural gas processing. The research will be integrated with educational and outreach programs intended for American Indian students, emphasizing the importance of sustainable energy.

3 Small Energy Firms to Collaborate with PNNL

Pacific Northwest National Laboratory is collaborating with three small businesses to address technical challenges concerning hydrogen for fuel cell cars, bio-coal and nanomaterial manufacturing.

ORNL to Collaborate with Five Small Businesses to Advance Energy Tech

Five small companies have been selected to partner with the Department of Energy's Oak Ridge National Laboratory to move technologies in commercial refrigeration systems, water power generation, bioenergy and battery manufacturing closer to the marketplace.

U.S. Department of Energy's INCITE Program Seeks Advanced Computational Research Proposals for 2018

The Department of Energy's INCITE program will be accepting proposals for high-impact, computationally intensive research campaigns in a broad array of science, engineering, and computer science domains.

New Berkeley Lab Project Turns Waste Heat to Electricity

A new Berkeley Lab project seeks to efficiently capture waste heat and convert it to electricity, potentially saving California up to $385 million per year. With a $2-million grant from the California Energy Commission, Berkeley Lab scientists will work with Alphabet Energy to create a cost-effective thermoelectric waste heat recovery system.

New SLAC Theory Institute Aims to Speed Research on Exotic Materials at Light Sources

A new institute at the Department of Energy's SLAC National Accelerator Laboratory is using the power of theory to search for new types of materials that could revolutionize society - by making it possible, for instance, to transmit electricity over power lines with no loss.

Lenvio Inc. Exclusively Licenses ORNL Malware Behavior Detection Technology

Virginia-based Lenvio Inc. has exclusively licensed a cyber security technology from the Department of Energy's Oak Ridge National Laboratory that can quickly detect malicious behavior in software not previously identified as a threat.

Argonne Scientist and Nobel Laureate Alexei Abrikosov Dies at 88

Alexei Abrikosov, an acclaimed physicist at the U.S. Department of Energy's Argonne National Laboratory who received the 2003 Nobel Prize in Physics for his work on superconducting materials, died Wednesday, March 29. He was 88.

Jefferson Lab Accomplishes Critical Milestones Toward Completion of 12 GeV Upgrade

The Continuous Electron Beam Accelerator Facility (CEBAF) at the U.S. Department of Energy's Thomas Jefferson National Accelerator Facility has achieved two major commissioning milestones and is now entering the final stretch of work to conclude its first major upgrade. Recently, the CEBAF accelerator delivered electron beams into two of its experimental halls, Halls B and C, at energies not possible before the upgrade for commissioning of the experimental equipment currently in each hall. Data were recorded in each hall, which were then confirmed to be of sufficient quality to allow for particle identification, a primary indicator of good detector operation.

Valerie Taylor Named Argonne National Laboratory's Mathematics and Computer Science Division Director

Computer scientist Valerie Taylor has been appointed as the next director of the Mathematics and Computer Science division at Argonne, effective July 3, 2017.


Uncrowded Coils

A new fast and robust algorithm for computing stellarator coil shapes yields designs that are easier to build and maintain.

Fast Electrons and the Seeds of Disruption

Physicists measured fast electron populations. They achieved this first-of-its-kind result by seeing the effect of the fast electrons on the ablation rate of small frozen argon pellets.

Plasma Turbulence Generates Flow in Fusion Reactors

Heating the core of fusion reactors causes them to develop sheared rotation that can improve plasma performance.

The Roadmap to Quark Soup

Scientists discover new signposts in the quest to determine how matter from the early universe turned into the world we know today.

Neutrons Play the Lead to Protons in Dance Around "Double-Magic" Nucleus

Electric and magnetic properties of a radioactive atom provide unique insight into the nature of proton and neutron motion.

Ultrafast Imaging Reveals the Electron's New Clothes

Scientists use high-speed electrons to visualize "dress-like" distortions in the atomic lattice. This work reveals the vital role of electron-lattice interactions in manganites. This material could be used in data-storage devices with increased data density and reduced power requirements.

One Small Change Makes Solar Cells More Efficient

For years, scientists have explored using tiny drops of designer materials, called quantum dots, to make better solar cells. Adding small amounts of manganese decreases the ability of quantum dots to absorb light but increases the current produced by an average of 300%.

Electronic "Cyclones" at the Nanoscale

Through highly controlled synthesis, scientists controlled competing atomic forces to let spiral electronic structures form. These polar vortices can serve as a precursor to new phenomena in materials. The materials could be vital for ultra-low energy electronic devices.

In a Flash! A New Way for Making Ceramics

A new process controllably but instantly consolidates ceramic parts, potentially important for manufacturing.

Deciphering Material Properties at the Single-Atom Level

Scientists determine the precise location and identity of all 23,000 atoms in a nanoparticle.


Friday April 07, 2017, 11:05 AM

Champions in Science: Profile of Jonathan Kirzner

Department of Energy, Office of Science

Wednesday April 05, 2017, 12:05 PM

High-Schooler Solves College-Level Security Puzzle From Argonne, Sparks Interest in Career

Argonne National Laboratory

Tuesday March 28, 2017, 12:05 PM

Champions in Science: Profile of Jenica Jacobi

Department of Energy, Office of Science

Friday March 24, 2017, 10:40 AM

Great Neck South High School Wins Regional Science Bowl at Brookhaven Lab

Brookhaven National Laboratory

Wednesday February 15, 2017, 04:05 PM

Middle Schoolers Test Their Knowledge at Science Bowl Competition

Argonne National Laboratory

Friday January 27, 2017, 04:00 PM

Haslam Visits ORNL to Highlight State's Role in Discovering Tennessine

Oak Ridge National Laboratory

Tuesday November 08, 2016, 12:05 PM

Internship Program Helps Foster Development of Future Nuclear Scientists

Oak Ridge National Laboratory

Friday May 13, 2016, 04:05 PM

More Than 12,000 Explore Jefferson Lab During April 30 Open House

Thomas Jefferson National Accelerator Facility

Monday April 25, 2016, 05:05 PM

Giving Back to National Science Bowl

Ames Laboratory

Friday March 25, 2016, 12:05 PM

NMSU Undergrad Tackles 3D Particle Scattering Animations After Receiving JSA Research Assistantship

Thomas Jefferson National Accelerator Facility

Tuesday February 02, 2016, 10:05 AM

Shannon Greco: A Self-Described "STEM Education Zealot"

Princeton Plasma Physics Laboratory

Monday November 16, 2015, 04:05 PM

Rare Earths for Life: An 85th Birthday Visit with Mr. Rare Earth

Ames Laboratory

Tuesday October 20, 2015, 01:05 PM

Meet Robert Palomino: 'Give Everything a Shot!'

Brookhaven National Laboratory

Tuesday April 22, 2014, 11:30 AM

University of Utah Makes Solar Accessible

University of Utah

Wednesday March 06, 2013, 03:40 PM

Student Innovator at Rensselaer Polytechnic Institute Seeks Brighter, Smarter, and More Efficient LEDs

Rensselaer Polytechnic Institute (RPI)

Friday November 16, 2012, 10:00 AM

Texas Tech Energy Commerce Students, Community Light up Tent City

Texas Tech University

Wednesday November 23, 2011, 10:45 AM

Don't Get 'Frosted' Over Heating Your Home This Winter

Temple University

Wednesday July 06, 2011, 06:00 PM

New Research Center To Tackle Critical Challenges Related to Aircraft Design, Wind Energy, Smart Buildings

Rensselaer Polytechnic Institute (RPI)

Friday April 22, 2011, 09:00 AM

First Polymer Solar-Thermal Device Heats Home, Saves Money

Wake Forest University

Friday April 15, 2011, 12:25 PM

Like Superman, American University Will Get Its Energy from the Sun

American University

Thursday February 10, 2011, 05:00 PM

ARRA Grant to Help Fund Seminary Building Green Roof

University of Chicago

Tuesday December 07, 2010, 05:00 PM

UC San Diego Installing 2.8 Megawatt Fuel Cell to Anchor Energy Innovation Park

University of California San Diego

Monday November 01, 2010, 12:50 PM

Rensselaer Smart Lighting Engineering Research Center Announces First Deployment of New Technology on Campus

Rensselaer Polytechnic Institute (RPI)

Friday September 10, 2010, 12:40 PM

Ithaca College Will Host Regional Clean Energy Summit

Ithaca College

Tuesday July 27, 2010, 10:30 AM

Texas Governor Announces $8.4 Million Award to Create Renewable Energy Institute

Texas Tech University

Friday May 07, 2010, 04:20 PM

Creighton University to Offer New Alternative Energy Program

Creighton University

Wednesday May 05, 2010, 09:30 AM

National Engineering Program Seeks Subject Matter Experts in Energy

JETS Junior Engineering Technical Society

Wednesday April 21, 2010, 12:30 PM

Students Using Solar Power To Create Sustainable Solutions for Haiti, Peru

Rensselaer Polytechnic Institute (RPI)

Wednesday March 03, 2010, 07:00 PM

Helping Hydrogen: Student Inventor Tackles Challenge of Hydrogen Storage

Rensselaer Polytechnic Institute (RPI)

Thursday February 04, 2010, 02:00 PM

Turning Exercise into Electricity

Furman University

Thursday November 12, 2009, 12:45 PM

Campus Leaders Showing the Way to a Sustainable, Clean Energy Future

National Wildlife Federation (NWF)

Tuesday November 03, 2009, 04:20 PM

Furman University Receives $2.5 Million DOE Grant for Geothermal Project

Furman University

Thursday September 17, 2009, 02:45 PM

Could Sorghum Become a Significant Alternative Fuel Source?

Salisbury University

Wednesday September 16, 2009, 11:15 AM

Students Navigating the Hudson River With Hydrogen Fuel Cells

Rensselaer Polytechnic Institute (RPI)

Wednesday September 16, 2009, 10:00 AM

College Presidents Flock to D.C., Urge Senate to Pass Clean Energy Bill

National Wildlife Federation (NWF)

Wednesday July 01, 2009, 04:15 PM

Northeastern Announces New Professional Master's in Energy Systems

Northeastern University

Friday October 12, 2007, 09:35 AM

Kansas Rural Schools To Receive Wind Turbines

Kansas State University

Thursday August 17, 2006, 05:30 PM

High Gas Prices Here to Stay, Says Engineering Professor

Rowan University

Wednesday May 17, 2006, 06:45 PM

Time Use Expert's 7-Year Fight for Better Gas Mileage

University of Maryland, College Park




Scientists Watch a Molecule Protect Itself From Radiation Damage

Article ID: 672664

Released: 2017-04-07 14:05:18

Source Newsroom: SLAC National Accelerator Laboratory

  • Credit: Helmholtz-Zentrum Berlin

    An illustration shows how energy from light changes a 2-thiopyridone molecule. Optical light strikes the molecule, and it loses a proton bound to hydrogen. An X-ray probe allows scientists to follow selective bond breaking between nitrogen and its carbon and hydrogen neighbors.

When the molecules that carry the genetic code in our cells are exposed to harm, they have defenses against potential breakage and mutations.

For instance, when DNA is hit with ultraviolet light, it can lose excess energy from radiation by ejecting the core of a hydrogen atom — a single proton — to keep other chemical bonds in the system from breaking.

To gain insight into this process, researchers used X-ray laser pulses from the Linac Coherent Light Source (LCLS) at the Department of Energy’s SLAC National Accelerator Laboratory to investigate how energy from light transforms a relatively simple molecule, 2-thiopyridone. This molecule undergoes a chemical transformation that also occurs in the building blocks of DNA. The scientists looked at this process by probing the nitrogen atom in the molecule with X-ray pulses that lasted just femtoseconds, or quadrillionths of a second.

The results, published in Angewandte Chemie, are a step toward better understanding what’s called “excited state proton transfers” in DNA and other molecules.

“Right now, we want to keep it simple,” says lead author Sebastian Eckert, a doctoral student at the University of Potsdam and Helmholtz-Zentrum Berlin. “It’s easier to look at the effects of photoexcitation in 2-thiopyridone because this molecule is small enough to understand and has only one nitrogen atom. We are among the first at LCLS to look at nitrogen at this energy, so it’s somewhat of a pilot experiment.”

This is also the first time the method, known as resonant inelastic X-ray scattering or RIXS, has been used to look at molecular changes involving nitrogen that happen in femtoseconds. This short timescale is important because that’s how fast protons are kicked away from molecules exposed to light, and it requires brilliant X-rays to see these ultrafast changes.

“LCLS is the only X-ray light source that can provide enough photons – particles of light,” says co-author Munira Khalil, a professor at the University of Washington. “Our detection mechanism is ‘photon-hungry’ and requires intense pulses of light to capture the effect we want to see.”

In the study, the researchers used an optical laser to initiate changes in the molecule, followed by an LCLS X-ray probe that allowed them to see movements in the bonds.

“We look for a resonance effect – a signature that lets us know we’ve tuned the X-rays to an energy that ensures we’re only examining changes related to or near the nitrogen atom,” says Mike Minitti, staff scientist at LCLS and co-author of the paper.

These “on-resonance” studies amplify the signal in a way that scientists can clearly interpret how X-rays interact with the sample.

The research team looked primarily at the bonds between atoms neighboring nitrogen, and confirmed that optical light breaks nitrogen-hydrogen bonds. 

“We were also able to confirm that the X-rays used to probe the sample don’t break the nitrogen-hydrogen bond, so the probe itself does not create an artificial effect. The X-ray energy is instead transferred to a bond between nitrogen and carbon atoms, rupturing it,” says Jesper Norell, a doctoral student at Stockholm University and co-author of the paper.

Next, the collaboration will use the same approach to study more complex molecules and gain insight into the wide class of photochemical reactions. 

LCLS is a DOE Office of Science User Facility. In addition to LCLS, researchers from the University of Potsdam, Helmhotz-Zentrum Berlin, Stockholm University and the University of Washington contributed expertise to this study. The X-ray-induced structural changes at LCLS were compared to observations at the Synchrotron Radiation Source BESSY II.

Citation: Eckert et al., Angewandte Chemie, 4 April 2017 (10.1002/anie.201700239)


SLAC is a multi-program laboratory exploring frontier questions in photon science, astrophysics, particle physics and accelerator research. Located in Menlo Park, Calif., SLAC is operated by Stanford University for the U.S. Department of Energy's Office of Science. For more information, please visit slac.stanford.edu.

SLAC National Accelerator Laboratory is supported by the Office of Science of the U.S. Department of Energy. The Office of Science is the single largest supporter of basic research in the physical sciences in the United States, and is working to address some of the most pressing challenges of our time. For more information, please visit science.energy.gov.